NYC Resistor

We learn, share, and make things

How to Identify Polymers with Burnination

Confirmed: Moleskine notebooks contain PVC or other chlorinated plastics. Do not laser cut them for your safety and the safety of your laser cutter.

Adam brought his laptop in to etch today. As we all know, laser cutting PVC is bad and releases chlorine gas (which is corrosive and bad for you and your machine.) Adam’s laptop was made of an unknown polymer, and we wanted to make sure we didn’t damage our new lazzzor. Luckily, there is an easy way to determine if a plastic is okay to etch. Watch the video below, and check out this guide to polymer identification for full details. There is actually a suite of tests you use to determine the type of plastic, but the burning one is the most fun, as well as the one that detects chlorine. Enjoy!


Polymer Identification by Burnination from Zach 'Iowa' Hoeken on Vimeo.

21 comments
  • phooky

    Oh god. That’s… that’s really what my voice sounds like, isn’t it.

    I’m going to laser-etch my trachea next.

  • http://dailydiy.com/2008/08/28/how-toxic-is-it/ Daily DIY Network – Science Projects Plans Guides » Blog Archive » How toxic is it?!?

    [...] The crew at NYCResistor conducted a series of “burnination” experiments to determine the chlorine content of materials before running them through a laser cutter. They confirm recent suspicions that moleskine notebook covers contain the PVC or other chlorinated plastics. Smart move – too often I’m left wondering, “how toxic is that?” after accidentally(or intentionally) melting/burning/exploding something. More info on their technique – How to Identify Polymers with Burnination [...]

  • http://www.developages.com/how-toxic-is-it/41198 How toxic is it?!? » Developages – Development and Technology Blog

    [...] The crew at NYCResistor conducted a series of “burnination” experiments to determine the chlorine content of materials before running them through a laser cutter. They confirm recent suspicions that moleskine notebook covers contain the PVC or other chlorinated plastics. Smart move – too often I’m left wondering, “how toxic is that?” after accidentally(or intentionally) melting/burning/exploding something. More info on their technique – How to Identify Polymers with Burnination [...]

  • http://www.simreal.com Edwin

    Oh yeah, I hear yah; it’s always disturbing to see/hear yourself (though I suppose you can get used to it with practice).

    I see myself in pics or video and I’m always, omg, what dork!

  • http://www.simreal.com Edwin

    Oh yeah, Chlorine; for extra credit in junior high science class, I made a quart jar of chlorine. My teacher, clearly, was an idiot.

    When I aired it out after class, a huge mistake, I ended up with the most amazing headache.

  • Dave

    If Chlorine is bad, Fluorine should also be bad. Thus, you probably shouldn’t burn/laser-etch Teflon:

    http://en.wikipedia.org/wiki/Polytetrafluoroethylene

    But, the question is, what will the flame test response be for Fluorine?

  • winnie

    i love you, phooky. you are the awesome.

  • http://greenertrends.com/2008/08/28/plastics-fire-poisons-fun/ Plastics + Fire – Poisons = Fun

    [...] been curious about what’s in your plastic?  The fellas at NYCResistor (a DIY group, not an underground insurgency) have a handy video to show us if you’ve got some [...]

  • phooky

    PTFE appears to be reasonably safe. Fluorine is so electronegative I doubt our puny laser can pry it from whatever it’s currently bound to.

  • Seth Morabito

    Phooky, you’re famous! And to think I knew you when you were a NOBODY.

  • Arthur

    here’s the chemistry basis… the copper ions from the solid copper wire combines with the freed up chloride (in the burnt plastic) to form copper chloride… which burns green:

    http://jchemed.chem.wisc.edu/jcesoft/cca/cca2/MAIN/FLAME/CD2R1.HTM

  • Arthur

    also remember that a propane torch releases CO (ie: carbon monoxide) which is poisonous. If you get a headache while burning “safe non-PVC’s”, it could be because of the CO.

  • http://www.nycresistor.com/2008/10/25/lazer-etching-a-moleskin/ != Lazer etching a Moleskin » NYC Resistor » Electronics, Hacking, Classes, and Workspace.

    [...] we got the Lazor at NYCR, Adam discovered that Moleskin’s have PVC (not good) in the leather and lazering such a thing could be harmful [...]

  • Darin

    thanks for putting this up, as a pipefitter/welder, I’m all the time put in positions where things around me get burned up, now I can at least test some of them to know what I should absolutely have removed before I get at what I’m working on directly. The air I breathe sometimes is bad enough, I certainly don’t need chlorine too.

  • http://www.TechShop.ws Lynne Angeloro

    GREAT info on keeping us from being dead! We’ll use this flame test here at TechShop to be sure no one kills us all in a cloud of Chlorine gas with one of our 2 laser cutters!

    THANKS!
    Lynne.

  • Ernie

    Hi.
    How much would it cost to perform a burn test of some heavy cardboard? I need to determine the degree of scorching it will suffer if I use it to laser cut a design.

    Thanks
    Ernie

  • shiiitt??

    whoa whoa whoa wait i got these lighters from beijing that are shaped like olympic torches that light green fire….shit? or is something else causing green fire?

  • Richard

    Never burn PTFE, it's fumes are cacinogenic, maybe fluorine?

  • RoganGunn

    No, don't worry – there are LOADS of different greens caused by various elements.

    In those lighters they use a metal compound to give off certain colours. Vibrant green is nickel and it's compounds/salts, or bluey-green may be a copper compound. All the harmful stuff would be too expensive to put on a cheapo lighter. (E.g. Barium or Boron compounds.)

    There's an admittedly incomplete list here: http://en.wikipedia.org/wiki/Flame_test

    Hope this helps! Though you should have paid attention in chemistry at school… ;-)

  • osnos

    Fluorine is correct. Which, with the available hydrogen in the atmosphere (moisture), will form hydrofluoric acid. It will likely fog up your glass optics. Don't burn PTFE.

  • Jerry Rutherford

    Very nicely done. I have been looking up the data sheets, etc. This is a good quick test. Thanks! (I have a 35w Epilog laser) I wonder how SPECTAR plastic will react? It smells VERY sweet… and even a tiny amount will make you woozy… so it is likely VERY BAD to burn it. http://www.eastman.com/Products/Pages/ProductHome.aspx?Product=71002011&list=Polymers but you can heat form it very well.